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While Gilde isn't a real-time video chatting app, it deserves a spot on this list for its unique approach.
Video calls, and even most voice calls, are free to any other Hangouts user.
With inserting a simple piece of HTML code, a floating chat button that doesn't interfere with your website design, and key features to help you do chat right, you'll be chatting to your website visitors without any cost.
Read More Get Started Chat via your mobile device by using our i Phone/i Pad or Android apps!
Google's own video and messaging app is one of the most popular ways to make voice and video calls from your Android phone, and that's not just because the app usually comes pre-installed.
The app grabs contacts from your Google account and phone's address book so that you can send text messages, place voice calls and start a Hangout, which is what Google calls a video chat.
For video calling, you can either send a pre-recorded video in a chat, or have a live video conversation.